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DAICEL CORPORATION Organic Chemical Products Company
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Caprolactone derivatives

PLACCEL M – Caprolactone Monomer

Applications Products Appearance Features
Modifier for Coatings and Adhesives PLACCEL M Liquid PLACCEL M is a cyclic ester. It features excellent chemical reactivity; allowing it to various resins and organic compounds in order to increase their compatibility, solubility, flexibility and reactivity.

PLACCEL 200 – Polycaprolactone Diols

Polycaprolactone diols have more excellent UV-resistance and heat resistance compared to polyether diols, and a higher water resistance compared to adipate-based polyester diols. The PLACCEL 200 series contains diols of various molecular weights and initiating materials, allowing for each to offer unique benefits. Typical applications include polyurethane coatings, adhesives, sealants, and elastomers.
Applications Products Appearance Features
Coatings, Adhesives PLACCEL 204B Liquid Polycaprolactone diol (Mean molecular weight 400).
Coatings, Adhesives PLACCEL 204HGT Liquid Polycaprolactone diol (Mean molecular weight 400)
Coatings, Adhesives PLACCEL 205 Paste Polycaprolactone diol (Mean molecular weight 530)
Coatings, Adhesives PLACCEL 205U Liquid Polycaprolactone diol (Mean molecular weight 530), Low viscosity
Coatings, Adhesives PLACCEL 205UT Liquid Polycaprolactone diol (Mean molecular weight 530), Low viscosity, Improved hydrolysis resistance
Coatings, Adhesives PLACCEL 205H Liquid Polycaprolactone diol (Mean molecular weight 530), Improved hydrolysis resistance
Coatings, Adhesives PLACCEL L205AL Liquid Polycaprolactone diol (Mean molecular weight 500).  Excellent scratch resistance
Coatings, Adhesives PLACCEL 205K Liquid Polycaprolactone diol (Mean molecular weight 530).  Developmental
Coatings, Adhesives PLACCEL 206BA Paste Polycaprolactone diol (Mean molecular weight 600) Developmental
Coatings, Adhesives PLACCEL 207HGT Paste Polycaprolactone diol (Mean molecular weight 750) Developmental
Coatings, Adhesives, Sealants PLACCEL 208 Wax Polycaprolactone diol (Mean molecular weight 830)
Coatings, Adhesives, Sealants PLACCEL 208U Paste Polycaprolactone diol (Mean molecular weight 830), Low viscosity
Adhesives, Sealants, Elastomers PLACCEL 210 Wax Polycaprolactone diol (Mean molecular weight 1000)
Adhesives, Sealants, Elastomers PLACCEL 210N Wax Polycaprolactone diol (Mean molecular weight 1000) with narrow molecular distribution.  Improved abrasion resistance and compression set resistance.
Adhesives, Sealants, Elastomers PLACCEL 210B Wax Polycaprolactone diol (Mean molecular weight 1000) with narrow molecular distribution
Adhesives, Sealants, Elastomers PLACCEL 210CP Paste Polycaprolactone diol (Mean molecular weight 1000) with narrow molecular distribution
Adhesives, Sealants, Elastomers PLACCEL 212 Wax Polycaprolactone diol (Mean molecular weight 1250)
Adhesives, Sealants, Elastomers PLACCEL 212CP Wax Polycaprolactone diol (Mean molecular weight 1250) with narrow molecular distribution
Adhesives, Sealants, Elastomers PLACCEL 212UA Wax Polycaprolactone diol (Mean molecular weight 1250) with narrow molecular distribution
Adhesives, Sealants, Elastomers PLACCEL L212AL Liquid Polycaprolactone diol (Mean molecular weight 1250), Liquid type
Adhesives, Sealants, Elastomers PLACCEL 220 Wax Polycaprolactone diol (Mean molecular weight 2000)
Adhesives, Sealants, Elastomers PLACCEL 220N Wax Polycaprolactone diol (Mean molecular weight 2000) with narrow molecular distribution.  Improved abrasion resistance and compression set resistance.
Adhesives, Sealants, Elastomers PLACCEL 220NT Wax Polycaprolactone diol (Mean molecular weight 2000) with narrow molecular distribution. Improved hydrolysis resistance and abrasion resistance.  Developmental
Adhesives, Sealants, Elastomers PLACCEL 220BT Wax Polycaprolactone diol (Mean molecular weight 2000) with narrow molecular distribution, Improved hydrolysis resistance
Adhesives, Sealants, Elastomers PLACCEL 220CPB Wax Polycaprolactone diol (Mean molecular weight 2000) with narrow molecular distribution
Adhesives, Sealants, Elastomers PLACCEL 220CPT Wax Polycaprolactone diol (Mean molecular weight 2000) with narrow molecular distribution, Improved hydrolysis resistance
Adhesives, Sealants, Elastomers PLACCEL 220CPK Wax Polycaprolactone diol (Mean molecular weight 2000) with narrow molecular distribution. Developmental
Adhesives, Sealants, Elastomers PLACCEL 220UA Wax Polycaprolactone diol (Mean molecular weight 2000) with narrow molecular distribution
Adhesives, Sealants, Elastomers PLACCEL L220AL Liquid Polycaprolactone diol (Mean molecular weight 2000), Liquid type with excellent scratch resistance
Adhesives, Sealants, Elastomers PLACCEL T2205T Wax Polyether-ester diol (Mean molecular weight 2000), Low viscosity, Cold resistance, Improved hydrolysis resistance
Adhesives, Sealants PLACCEL 230 Wax Polycaprolactone diol (Mean molecular weight 3000)
Adhesives, Sealants PLACCEL 230N Wax Polycaprolactone diol (Mean molecular weight 3000) with narrow molecular distribution.  Improved abrasion resistance and compression set resistance.
Adhesives, Sealants PLACCEL 240 Wax Polycaprolactone diol (Mean molecular weight 4000)
Adhesives, Sealants PLACCEL 220EB Liquid Aliphatic polyester diol (Mean molecular weight 2000), High hydrolysis resistance, Adhesion property
Adhesives, Sealants, elastomers PLACCEL 220EC Liquid Polycarbonate-ester diol (Mean molecular weight 2000), High hydrolysis resistance. Developmental

PLACCEL 300 – Triols

Polycaprolactones triols are utilized primarily in Polyurethane coatings, adhesives, and foam, as well as in epoxy resin formulations as a flexibility modifier.  The PLACCEL 300 series includes grades of various molecular weights so crosslinking can be controlled more precisely.
Applications Products Appearance Features
Coatings and Adhesives, Crosslinker PLACCEL 303 Liquid Polycaprolactone triol (Mean molecular weight 310)
Coatings and Adhesives, Crosslinker PLACCEL 305 Liquid Polycaprolactone triol (Mean molecular weight 550)
Coatings and Adhesives, Crosslinker PLACCEL 305T Liquid Polycaprolactone triol (Mean molecular weight 550), Improved hydrolysis resistance
Coatings and Adhesives PLACCEL 308 Liquid Polycaprolactone triol (Mean molecular weight 850)
Coatings and Adhesives PLACCEL 309 Liquid Polycaprolactone triol (Mean molecular weight 900)
Coatings and Adhesives PLACCEL 312 Wax Polycaprolactone triol (Mean molecular weight 1250)
Coatings and Adhesives PLACCEL 320 Wax Polycaprolactone triol (Mean molecular weight 2000)
Coatings and Adhesives PLACCEL L320AL Liquid Polycaprolactone triol (Mean molecular weight 2000), Liquid type, excellent scratch resistance
Coatings and Adhesives PLACCEL 330NT Wax Polycaprolactone triol (Mean molecular weight 3000), Improved hydrolysis resistance, abrasion resistance, and compression set resistance.  Developmental

PLACCEL 400 – Tetraol

PLACCEL 410 is a polycaprolactone tetraol.  It can be used as a crosslinking agent and raw material for polyurethane and epoxy coatings
Applications Products Appearance Features
Coatings, Crosslinker PLACCEL 410 Liquid Polycaprolactone tetraol (Mean molecular weight 1030)

PLACCEL CD – Polycarbonate Diols

Polycarbonate diols can also be used in polyurethane applications.  They are characterized by their superior heat and moisture resistance compared to both polyether and polyester diols.  In addition, they have superior abrasion resistance and a higher tensile modulus.
Applications Products Appearance Features
Coatings, Sealants, Elastomers PLACCEL CD210 Wax Polycarbonate diol (Mean molecular weight 1000)
Coatings, Sealants, Elastomers PLACCEL CD220 Wax Polycarbonate diol (Mean molecular weight 2000)
Coatings, Sealants PLACCEL CD205PL Liquid Polycarbonate diol (Mean molecular weight 500), Liquid type, Not TSCA listed
Coatings, Sealants, Elastomers PLACCEL CD220PL Liquid Polycarbonate diol (Mean molecular weight 2000), Liquid type, Not TSCA listed

PLACCEL F – Caprolactone modified (meth)acrylates

PLACCEL F series materials are macro monomers with a (meth)acrylic double bond.  They have both a radically polymerizable (meth)acrylic double bond, and a primary hydroxyl group which is highly reactive with hardening agents such as isocyanates and/or melamine.
Applications Products Appearance Features
Resins PLACCEL FA1 Liquid Caprolactone modified hydroxyl acrylate (Mean molecular weight 230)
Resins PLACCEL FA1DDM Liquid Caprolactone modified hydroxyl acrylate (Mean molecular weight 230)
Resins PLACCEL FA2D Liquid Caprolactone modified hydroxyl acrylate (Mean molecular weight 344)
Resins PLACCEL FA2K Liquid Caprolactone modified hydroxyl acrylate (Mean molecular weight 344)
Resins PLACCEL FA4DT Wax Caprolactone modified hydroxyl acrylate (Mean molecular weight 573)
Resins PLACCEL FA5 Wax Caprolactone modified hydroxyl acrylate (Mean molecular weight 686)
Resins PLACCEL FM1 Liquid Caprolactone modified hydroxyl methacrylate (Mean molecular weight 244)
Resins PLACCEL FM1D Liquid Caprolactone modified hydroxyl methacrylate (Mean molecular weight 244)
Resins PLACCEL FM2D Liquid Caprolactone modified hydroxyl methacrylate (Mean molecular weight 358)
Resins PLACCEL FM3 Paste Caprolactone modified hydroxyl methacrylate (Mean molecular weight 473)
Resins PLACCEL FM5 Wax Caprolactone modified hydroxyl methacrylate (Mean molecular weight 701)
Resins PLACCEL FM5L Liquid Caprolactone modified hydroxyl methacrylate (Mean molecular weight 701)

PLACCEL H – Thermoplastic Polycaprolactone

PLACCEL H series materials are highly crystallized, aliphatic polyester thermoplastic resins with a melting point of 60°C, and a glass transition temperature of -60°C.  Other properties include  biodegradability and high resistance to thermal degradation.  These materials can be used in a variety of applications, including hot melt adhesives, medical devices, and biodegradable packaging.
Applications Products Appearance Features
Resins PLACCEL H1P Granular High molecular weight Polycaprolactone (Mean molecular weight 10000), Biodegradability, High crystallinity, Low mp(60C)
Biodegradable Polymer High Molecular Weight PCL (Developmental Stage) Pellet Click Here to Learn More about This Product!

PLACCEL Others

Applications Products Appearance Features
Resins PLACCEL P3403 Liquid Polyether-ester triol (Mean molecular weight 4000)
Resins PLACCEL HEMAC1 Liquid Carbonate modified hydroxyl methacrylate (Mean molecular weight 260)
Resins PLACCEL CDE9P Liquid Caprolactone modified polyester polyol

Developmental Grades – Special Polycaprolactone Triols

This new grade of PLACCEL triol is specifically designed to improve the flexibility/toughness of PU coatings, while maintaining high chemical, scratch and weathering resistance.
Applications Products Appearance Features
PU Coatings PLACCEL E2390 Liquid Polycaprolactone triol (Mean molecular weight 600) Excellent Chemical resistance
PU Coatings PLACCEL E2394 Liquid Polycaprolactone triol (Mean molecular weight 1000) Flexibility, High Chemical Resistance
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